New Mixed-ligand Isocyanide Diphosphine Ruthenium(II) Derivatives. Synthesis of a Potential Metal-containing Tetradentate Ligand

DOI: 10.1039/DT9950001069

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1069 - 1072 (1995)

Update date:2022-09-26

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Authors:

Ruiz, Javier

Riera, Victor

Vivanco, Marilin

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Article abstract of DOI:10.1039/DT9950001069

Reaction of trans- with an excess of Ph2PCH2PPh2 (dppm) in refluxing toluene gave two complexes cis,cis,trans- 1 and mer-Cl 2a; whereas in the reaction of trans- with dppm under the same conditions only mer-Cl 2b was obtained.Complex 1 reacted with TlPF6 in CH2Cl2 to give PF6 3, a cationic complex containing both a monodentate and a chelated dppm ligand.Complex 1 is remarkable in having two monohapto dppm ligands and can be used in the synthesis of heterometallic species.Thus, treatment of 1 with AgClO4 or HgCl2 gave the heterometallic complex <(dppm)(PhNC)2ClRu(μ-dppm)AgCl>ClO4 4 or <<(dppm)(PhNC)2ClRu(μ-dppm)HgCl2>2>Cl2 5 respectively.

Full text of DOI:10.1039/DT9950001069

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