An Efficient Synthesis of the First Electroactive Phosphorus-containing Bisferrocene Macrocycles

DOI: 10.1039/c39950000585

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 585 - 588 (1995)

Update date:2022-07-31

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Authors:

Delavaux-Nicot, Beatrice

Guari, Yannick

Douziech, Benedicte

Mathieu, Rene

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Article abstract of DOI:10.1039/c39950000585

Condensation reactions of the phosphodihydrazide XP(Ph)(NMeNH2)2 (X = O 1a, S 1b) with ferrocene-1,1'-dicarboxaldehyde 2 afford in good yield the first examples of phosphorus ferrocenyl macrocycles Fe2Fe (X = O 3a, S 3b) and 3b can be converted to the new compounds Fe2Fe 5 and 2Fe>2 6 by reaction with, respectively, LAH and CF3SO3Me; 5 represents a novel prototype of an anion receptor which electrochemically recognises the H2PO4^-, HSO4^- and Cl^- anions.

Full text of DOI:10.1039/c39950000585

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