Angewandte Chemie - International Edition in English p. 2251 - 2253 (1996)
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Hydrogenation of 1-hexene is eight times faster with the rhodacarbonate complex 1 than with [RhCl(PPh3)3]. The sulfur atom bound to the open face factors the interaction of the rhodium center with the more active B-H vertices situated on this face.
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