Angewandte Chemie - International Edition in English p. 2251 - 2253 (1996)
Update date:2022-07-29
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Hydrogenation of 1-hexene is eight times faster with the rhodacarbonate complex 1 than with [RhCl(PPh3)3]. The sulfur atom bound to the open face factors the interaction of the rhodium center with the more active B-H vertices situated on this face.
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Doi:10.1016/0223-5234(94)90069-8
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(1994)Doi:10.1016/S0040-4039(00)73115-7
(1994)Doi:10.1016/j.bmc.2006.03.001
(2006)Doi:10.1021/jo402181w
(2014)Doi:10.1007/BF00477531
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