Two counterintuitive routes to an iron alkylidyne complex

DOI: 10.1021/om00004a007

Source and publish data:

Organometallics p. 1562 - 1564 (1995)

Update date:2022-08-03

Topics:

Authors:

Anderson, Stephen

Hill, Anthony F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00004a007

The cationic aminomethylidyne complex [Fe-(≡CNⁱPr₂)(CO)₃(PPh₃) ⁺ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η²-OCNⁱPr₂)(CF₃)(CO) ₂(PPh₃)] and (ii) O-trifluoro-acetylation of the carbamoylate [Fe{C(=O)NⁱPr₂}(CO)₄]-Li, a reaction which shows an unusual solvent dependence.

Full text of DOI:10.1021/om00004a007

Products guided by the article

Product name:[Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃

Cas No:164072-08-6

R&D Labs maybe for 164072-08-6

Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Hunan Dinuo Pharmaceutical Co.,Ltd.

Contact:86-731-88280100*8561

Address:Bio-pharmaceutical industrial park, Liuyang, Hunan, China
NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA
shanghai meicheng chemical co .,ltd(expird)

Contact:+86-21-50677091

Address:Room 302, Building 7, No.1000, Jinhai Road

Relevant to this article

Synthesis of zearalenone-16-β,D-glucoside and zearalenone-16-sulfate: A tale of protecting resorcylic acid lactones for regiocontrolled conjugation

Doi:10.3762/bjoc.10.112
(2014)
Cascade nitration/cyclization of 1,7-enynes with tBuONO and H₂O: One-pot self-assembly of pyrrolo[4,3,2-de]quinolinones

Doi:10.1002/anie.201404192
(2014)
Stereocontrolled conversion of 3-unsubstituted isoxazole compounds into Z-β-siloxyacrylonitriles. A new method for the regioselective synthesis of β-enaminoketones

Doi:10.1080/00397919508012661
(1995)
Syntheses, Reactivities and Molecular Structures of Tungsten Complexes containing the Diphenylphosphinodithioformato Ligand

Doi:10.1039/DT9950001305
(1995)
Anti-markovnikov hydroamination of aromatic alkenes with secondary amines catalyzed by easily accessible yttrium complexes

Doi:10.1002/cctc.201402012
(2014)
Benzophenone-nucleoside derivatives as telomerase inhibitors: Design, synthesis and anticancer evaluation in vitro and in vivo

Doi:10.1016/j.ejmech.2016.09.011
(2016)

Article Doi