Two counterintuitive routes to an iron alkylidyne complex

DOI: 10.1021/om00004a007

Source and publish data:

Organometallics p. 1562 - 1564 (1995)

Update date:2022-08-03

Topics:

Authors:

Anderson, Stephen

Hill, Anthony F.

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Article abstract of DOI:10.1021/om00004a007

The cationic aminomethylidyne complex [Fe-(≡CNⁱPr₂)(CO)₃(PPh₃) ⁺ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η²-OCNⁱPr₂)(CF₃)(CO) ₂(PPh₃)] and (ii) O-trifluoro-acetylation of the carbamoylate [Fe{C(=O)NⁱPr₂}(CO)₄]-Li, a reaction which shows an unusual solvent dependence.

Full text of DOI:10.1021/om00004a007

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