Aldol Reactions of Ethyl N-Benzyl-N-methylglycinate and of its Borane Adduct: Selective Access to Syn or Anti α-Amino-β-hydroxyesters

DOI: 10.1039/c39950000487

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 487 - 490 (1995)

Update date:2022-07-29

Topics:

Authors:

Ferey, Vincent

Gall, Thierry Le

Mioskowski, Charles

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950000487

Procedures are developed for the condensation of aldehydes with ethyl N-benzyl-N-methylglycinate 1 and with its borane adduct 2, which selectively afford the corresponding syn and anti aldols, respectively.

Full text of DOI:10.1039/c39950000487

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₆H₅CH₂N(BH₃)(CH₃)CH₂COOC₂H₅

Cas No:164167-45-7

R&D Labs maybe for 164167-45-7

Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District
Suzhou Jingye Medicine & Chemical Co., Ltd

website:http://www.jingyechem.cn

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Wuhan HengHeDa Pharm Co., Ltd

Contact:86-27-84888681

Address:Wuhan economic & technology development zone
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China

Relevant to this article

Asymmetric palladium-catalyzed allylic alkylation using dialkylzinc reagents: A remarkable ligand effect

Doi:10.1002/anie.201309074
(2014)
Functionalized chloroenamines in aminocyclopropane synthesis - XVII. 3,5-Cyclopiperidine-4-carboxamides with an unsubstituted 4-amino moiety - A synthetic and a conformational study

Doi:10.1016/0040-4020(95)00092-M
(1995)
Doi:10.1021/ja01072a085
(1964)
Monopentamethylcyclopentadienyl isocyanide, amine and imido tantalum(V) complexes. X-ray crystal structure of *Cl4(CN-2,6-Me2C6H3)>

Doi:10.1016/0022-328X(94)05236-5
(1995)
Polycyclic N-heterocyclic compounds. Part 80: Synthesis and evaluation of effects on in vitro pentosidine formation of 5,6-dihydro[1]benzothieno[3′, 2′:2,3]thiepino[4,5-d]pyrimidine and related compounds

Doi:10.1002/jhet.1709
(2014)
Doi:10.1021/jo01270a052
(1968)

Article Doi