Synthesis and reactions of N,N-dichloroperfluoroalkanesulfonylamides

DOI: 10.1016/0022-1139(93)03034-J

Source and publish data:

Journal of Fluorine Chemistry p. 7 - 8 (1994)

Update date:2022-08-04

Topics:

Authors:

Zhu, Shi-zheng

Zhou, Cheng-ming

Li, Ai-wen

Hu, Bin Hu, Bin

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Article abstract of DOI:10.1016/0022-1139(93)03034-J

Reactions of N,N-dichloroperfluoroalkanesulfonylamides with alkenes, benzene, dimethyl sulfide and dimethyl sulfoxide in the presence of zinc dust gave addition or insertion products via the fluoroalkanesulfonylnitrene intermediate.On heating R_fSO2NCl2 in the presence of alkene without zinc, 1:1 addition products were formed via a free-radical mechanism.

Full text of DOI:10.1016/0022-1139(93)03034-J

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