Distortions in Six-co-ordinate Complexes of Molybdenum(II) and Tungsten(II). Crystal Structures of mer-, cis,cis,cis- and

DOI: 10.1039/DT9950001315

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1315 - 1324 (1995)

Update date:2022-08-05

Topics:

Authors:

Burrow, Timothy E.

Hughes, David L.

Lough, Alan J.

Maguire, Michael J.

Morris, Robert H.

Richards, Raymond L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001315

The red, diamagnetic complexes mer- 1 and 2 have been prepared by reaction of with CO in tetrahydrofuran.The crystal structure of 1 shows it to have a distorted octahedral geometry with mer-CO ligands .Reaction of CO with in toluene gives green, distorted octahedral cis,cis,cis- 3 .Reaction with gives burgundy, trigonal prismatic 4 .The physical properties of 1-4 and the structures of 1, 3 and 4 are discussed in terms of their distortions from regular octahedral or trigonal-prismatic geometries.A method of classifying such structures is proposed.

Full text of DOI:10.1039/DT9950001315

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:mer-tricarbonyl(methyldiphenylphosphine)bis(2,4,6-triisopropylbenzenethiolato)molybdenum(II)

Cas No:164411-09-0

R&D Labs maybe for 164411-09-0

ANTAI BIO-TECH CO LTD

website:http://www.antaibio.com

Contact:0086-21-65663057

Address:Room 2108, Building 2，No. 489 Zhengli Road，200433
Jiangsu Taihu New Materials Holding Co., Ltd

Contact:+86-519-86160108

Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China

Relevant to this article

Convergent Synthesis of (R,R)-6,12-Dimethylpentadecan-2-one, the Female Sex Pheromone of the Banded Cucumber Beetle by Iron Mediated Chirality Transfer

Doi:10.1016/0040-4020(95)00282-D
(1995)
Mild and efficient chemoselective synthesis of acetals and geminal diacetates (acylals) from aldehydes using lanthanum(III) nitrate hexahydrate

Doi:10.1080/00397910801986010
(2008)
Synthesis and antioxidant activity evaluation of new hexahydropyrimido[5,4-c]quinoline-2,5-diones and 2-thioxohexahydropyrimido[5,4-c]quinoline-5-ones obtained by Biginelli reaction in two steps

Doi:10.1016/j.ejmech.2007.07.012
(2008)
Nucleophilic fluoroalkylation of α,β-enones, arynes, and activated alkynes with fluorinated sulfones: Probing the hard/soft nature of fluorinated carbanions

Doi:10.1021/jo702479z
(2008)
Catalytic amide-mediated methyl transfer from silanes to alkenes in Fujiwara-Moritani oxidative coupling

Doi:10.1002/anie.200800815
(2008)
Doi:10.1016/S0022-328X(00)80048-0
(1963)

Article Doi