Distortions in Six-co-ordinate Complexes of Molybdenum(II) and Tungsten(II). Crystal Structures of mer-, cis,cis,cis- and

DOI: 10.1039/DT9950001315

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1315 - 1324 (1995)

Update date:2022-08-05

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Authors:

Burrow, Timothy E.

Hughes, David L.

Lough, Alan J.

Maguire, Michael J.

Morris, Robert H.

Richards, Raymond L.

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Article abstract of DOI:10.1039/DT9950001315

The red, diamagnetic complexes mer- 1 and 2 have been prepared by reaction of with CO in tetrahydrofuran.The crystal structure of 1 shows it to have a distorted octahedral geometry with mer-CO ligands .Reaction of CO with in toluene gives green, distorted octahedral cis,cis,cis- 3 .Reaction with gives burgundy, trigonal prismatic 4 .The physical properties of 1-4 and the structures of 1, 3 and 4 are discussed in terms of their distortions from regular octahedral or trigonal-prismatic geometries.A method of classifying such structures is proposed.

Full text of DOI:10.1039/DT9950001315

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