Cationic arylmanganese(II) derivatives occurring in ion-pair forms with tetraphenylborate anions: Synthetic, structural, and magnetic studies

DOI: 10.1021/om00005a028

Source and publish data:

Organometallics p. 2265 - 2276 (1995)

Update date:2022-08-06

Topics:

Authors:

Solari, Euro

Musso, Fabrizio

Gallo, Emma

Floriani, Carlo

Re, Nazzareno

Chiesi-Villa, Angiola

Rizzoli, Corrado

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Article abstract of DOI:10.1021/om00005a028

We report a class of cationic manganese(II) aryl compounds stabilized by weak donor solvents or by interactions with the counteranion BPh₄^- to form ion-pair species. The parent compound used was Mn₃Mes₆ (1; Mes

Full text of DOI:10.1021/om00005a028

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Product name:((CH₃)3C₆H₂)Mn((C₂H₅)2O)3⁽¹⁺⁾*B(C₆H₅)4^(1-)=[((CH₃)3C₆H₂)Mn((C₂H₅)2O)3][B(C₆H₅)4]

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