A,B-Diheteropentalenes by a Tandem Intramolecular Diels-Alder/Reverse Diels-Alder Reaction Sequence. Application to the Synthesis of Thienofuran

DOI: 10.1071/CH9950593

Source and publish data:

Australian Journal of Chemistry p. 593 - 608 (1995)

Update date:2022-08-04

Topics:

Authors:

Buttery, Jarrod H.

Moursounidis, John

Wege, Dieter

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Article abstract of DOI:10.1071/CH9950593

Alkylation of 2-furylmethanethiol (28) with propargyl chloride gave the thioether (22) which on methoxycarbonylation afforded the acetylenic ester (30).On heating, this material underwent an intramolecular Diels-Alder reaction to give the tricyclic compou

Full text of DOI:10.1071/CH9950593

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