The Formation and Structural Characterisation of the transoid-η4(5e)-Butadienyl Ligand; Evidence for a 'Bent' Rhenium-Carbon Bond

DOI: 10.1039/c39950000593

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 593 - 596 (1995)

Update date:2022-08-03

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Authors:

Deeth, Robert J.

Dossett, Stephen J.

Green, Michael

Mahon, Mary F.

Rumble, Simon J.

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Article abstract of DOI:10.1039/c39950000593

Treatment of 2-PhC2Ph)2(η-C5H5)> with Li in THF affords the η²(3e)-vinyl/η²(2e)-alkyne complex (H)Ph>(η²-PhC2Ph)(η-C5H5)> and the transoid-η⁴(5e)-butadienyl complex 3-C(Ph)C(Ph)C(H)Ph>(η-C5H5)>, the latter containing a metal to carbon double bond and a novel 'bent' rhenium to carbon bond.

Full text of DOI:10.1039/c39950000593

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