Synthesis and Characterization of Phenylimidorhenium(V) Compounds containing Polypyridyl Ligands. Crystal Structures of mer-, trans-2 and trans-PF6 (bipy = 2,2'-bipyridine, terpy = 2,2':6',2''-terpyridine)

DOI: 10.1039/DT9950001733

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1733 - 1738 (1995)

Update date:2022-08-03

Topics:

Authors:

Bakir, Mohammed

Sullivan, B. Patrick

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001733

The reaction between mer- and aniline in refluxing o-xylene gave phenylimido compounds formulated as mer-.These compounds do not react with an alcohol (ROH) to form alkoxyimido compounds of the type cis-, but in the presence of an excess of the polypyridyl ligand, salts of the cation trans-(2+) were obtained.When salts of trans-(2+) were dissolved in MeCN solutions containing a few drops of concentrated hydrochloric acid rapid reactions occurred that resulted in the isolation of mer-.The salt trans-PF6 was prepared from the reaction between mer-trans- and 2,2':6',2''-terpyridine (terpy) in refluxing ethanol.The spectroscopic and electrochemical properties of these compounds were investigated and the structures of mer-, trans- and PF6 determined by X-ray crystallography.

Full text of DOI:10.1039/DT9950001733

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:mer-[Re(NPh)Cl₃(4,4'-dimethyl-2,2'-bipyridine)]

Cas No:165405-74-3

R&D Labs maybe for 165405-74-3

Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China
SHANGHAI SYSTEAM BIOCHEM CO., LTD

website:http://www.systeambc.com

Contact:86-021-58380978

Address:Building 87，Lane 669， Dong Jing Road Shanghai,P.R.China
Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China

Relevant to this article

Di- and Tri-metallic Complexes containing Two Bridging Cyclodiphosphazane Ligands: the Crystal Structure of 2>2>

Doi:10.1039/DT9950001933
(1995)
Synthesis of crown ether-linked discotic triphenylenes

Doi:10.1021/ol902637z
(2010)
Doi:10.1007/BF00471637
()
Doi:10.1021/ja01203a001
(1947)
Colorimetric chemosensors designed to provide high sensitivity for Hg ²⁺ in aqueous solutions

Doi:10.1016/j.dyepig.2012.06.023
(2013)
Synthesis, preliminary biological evaluation and molecular modeling of some new heterocyclic inhibitors of TACE

Doi:10.1016/j.ejmech.2011.09.018
(2011)

Article Doi