Chemoselective removal of allylic formyloxy group using SmI2

Article abstract of DOI:10.1080/00397919508011375

A variety of allylic formates are chemoselectively transformed into th corresponding olefins in excellent yields on treatment with SmI₂ in THF-HMPA-H₂O (20:5:1), even though allylic acetate and allylic ether groups are present in the same molecule.

Full text of DOI:10.1080/00397919508011375

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Chemoselective Removal of
Allylic Formyloxy Group Using
Sml2
K. Shibuya a & M. Shiratsuchi a
a Tokyo Research Laboratories , Kowa Co., Ltd. ,
2-17-43 Noguchi-cho, Higashimurayama, Tokyo, 189,
Japan
Published online: 23 Sep 2006.
To cite this article: K. Shibuya & M. Shiratsuchi (1995) Chemoselective Removal of
Allylic Formyloxy Group Using Sml2 , Synthetic Communications: An International
Journal for Rapid Communication of Synthetic Organic Chemistry, 25:3, 431-449, DOI:
10.1080/00397919508011375
To link to this article: http://dx.doi.org/10.1080/00397919508011375
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