Total synthesis of ganglioside GQ1b and the related polysialogangliosides

DOI: 10.1016/S0957-4166(00)80396-1

Source and publish data:

Tetrahedron Asymmetry p. 2493 - 2512 (1994)

Update date:2022-09-26

Topics: Chromatography Total synthesis Nucleophilic substitution Chemical Synthesis Ceramide Sialic acid Oligosaccharide

Authors:

Ishida Ishida

Kiso Kiso

Hasegawa

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Article abstract of DOI:10.1016/S0957-4166(00)80396-1

The first total synthesis of ganglio-series gangliosides GQ1b, GT1b and GD1b, which contain α-sialyl-(2 → 8)-α-sialic acid residue in the structure, will be described. Glycosylation of 2-(trimethylsilyl)ethyl O-(2-acetamido-6-O-benzyl-2-deoxy-3,4-O-isopro

Full text of DOI:10.1016/S0957-4166(00)80396-1

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Product name:2-(trimethylsilyl)ethyl O-(6-O-benzyl-2-deoxy-3,4-O-isopropylidene-2-phthalimido-β-D-galactopyranosyl)-(1<*>4)-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1<*>4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

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