Journal of the Chemical Society - Faraday Transactions p. 2585 - 2592 (1996)
Update date:2022-08-04
Topics:
Li, Hui
Zhou, Dejian
Huang, Chunhui
Xu, Jingmei
Li, Tiankai
Zhao, Xinsheng
Xia, Xiaohua
A bivalent zinc complex anion: bis(2-thione-1,3-dithiol-4,5-dimercapto)zinc, has been chosen to balance several non-linear optical (NLO) dye cations in the design and synthesis of a series of novel bis-chromophore complex dyes. The Langmuir film-forming properties of these new NLO complex dyes at the air/water interface, the stability and second-order non-linear optical properties of the monolayer and Langmuir-Blodgett multilayer films were investigated. Results show that both the film-forming properties and NLO coefficiencies were improved greatly when the zinc complex anion was incorporated into four types of NLO-active organic dyes.
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