Molecules with Twist Bent Bonds. A Comparison of the Thermal and Transition-Metal-Complex Promoted Rearrangements of Derivatives of trans-Bicyclohept-3-ene

DOI: 10.1016/S0040-4039(00)80613-9

Source and publish data:

Tetrahedron Letters p. 4803 - 4806 (1988)

Update date:2022-07-29

Topics:

Authors:

Gassman, Paul G.

Mlinaric-Majerski, Kata

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Article abstract of DOI:10.1016/S0040-4039(00)80613-9

7-Methyl-trans-bicyclo<4.1.0>hept-3-ene has been synthesized and the thermal and transition-metal-complex promoted rearrangements of trans-bicyclo<4.1.0>hept-3-ene, 7-methyl-trans-bicyclo<4.1.0>hept-3-ene, and 7,7-dimethyl-trans-bicyclo<4.1.0>hept-3-ene have been compared.

Full text of DOI:10.1016/S0040-4039(00)80613-9

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