The effect of trifluoromethyl substitution on the B=N bond in trifluoromethyl-dimethylaminoboranes, CF3(R)BNMe2: crystal and molecular structure of CF3(Et)(NCCH2)B*NHMe2

DOI: 10.1016/0022-328X(94)05344-B

Source and publish data:

Journal of Organometallic Chemistry p. 167 - 174 (1995)

Update date:2022-09-26

Topics:

Authors:

Brauer, David J.

Buerger, Hans

Dittmar, Thomas

Pawelke, Gottfried

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Article abstract of DOI:10.1016/0022-328X(94)05344-B

Chloro-trifluoromethyl-dimethylaminoborane, CF3(Cl)BNMe2 (I), has been prepared from Cl2BNMe2 using the reagent combination P(NEt2)3-CF3Br in sulpholane.Compound I undergoes <2+2> cycloaddition reactions with ^tBuNCO and Cl2BNMe2 to yield the fo

Full text of DOI:10.1016/0022-328X(94)05344-B

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