Journal of Organometallic Chemistry p. 95 - 104 (1995)
Update date:2022-08-02
Topics:
Albert, Joan
Granell, Jaume
Moragas, Rosa
Sales, Joaquim
Font-Bardia, Merce
Solans, Xavier
The action of Pd(AcO)2 on the imines C6RmH5-mCH=N(CH2)nC6H5 have been studied.Five-membered endo metallacycles were obtained from the imines 1a (R = 3,5-F2, n = 0), 1b (R = 3,5-F2, n = 1), 1c (R = 3,5-(MeO)2, n = 0) and 1d (R = 3,5-(MeO)2, n = 1), by activation of a C(aromatic)-H bond, in spite of the presence of MeO or F substituents on the carbon atom adjacent to the metallation position. 1H NMR spectra of the acetate bridged compounds
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(1995)