Novel alkylation-annulation reaction of fischer carbene complexes

DOI: 10.1021/om00008a004

Source and publish data:

Organometallics p. 3617 - 3619 (1995)

Update date:2022-07-30

Topics:

Authors:

Amin, Sk. Rasidul

Sawant, Sudhir S.

Puranik, Vedavati G.

Sarkar, Amitabha

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Article abstract of DOI:10.1021/om00008a004

Alkylation of aminocarbene complexes (CO)₅M=C(CH₃)(NHR) with dichloromethane or dibromomethane under PTC conditions triggers an annulation reaction leading to novel cyclic products. This is the first example of such reactivity of Fis

Full text of DOI:10.1021/om00008a004

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Product name:(CO)5Cr(C₄H₃(CH₃)N₂(CH₂C₆H₅)2)

Cas No:167112-51-8

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