Palladium catalyzed reductive deprotection of alloc: Transprotection and peptide bond formation

DOI: 10.1016/0040-4039(95)00449-M

Source and publish data:

Tetrahedron Letters p. 3129 - 3132 (1995)

Update date:2022-07-30

Topics:

Authors:

Beugelmans, Rene

Neuville, Luc

Bois-Choussy, Michele

Chastanet, Jacqueline

Zhu, Jieping

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00449-M

N-allyloxycarbonyl group could be efficiently removed using sodium borohydride as hydride donor in the presence of catalytic amount of palladium (0). The conditions were applied to chemoselective protecting group transformation (transprotection) and peptide bond formation.

Full text of DOI:10.1016/0040-4039(95)00449-M

Products guided by the article

Product name:(S)-2-Amino-N-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-1-(3-hydroxy-phenyl)-ethyl]-propionamide

Cas No:167423-70-3

R&D Labs maybe for 167423-70-3

Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
SNC | GOOD FORTUNE

Contact:0086-22-2822 1962 / 2822 1963

Address:B-808, No. 1, North-South Street, Hexi District,
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Melone Pharmaceutical Co., ltd

Contact:+86-411 82593920, 82593631

Address:No 232, JInma Roda, Development Zone, Dalian, China
Huangshi Shennong Chemical Technology Co., Ltd

Contact:+86-714-3072290

Address:Eastern industrial park , Tieshan district , Huangshi city ,Hubei province , China

Relevant to this article

Doi:10.1021/jo01254a010
(1969)
Doi:10.1021/jo01068a041
(1961)
Organocatalytic Enantioselective Conia-Ene-Type Carbocyclization of Ynamide Cyclohexanones: Regiodivergent Synthesis of Morphans and Normorphans

Doi:10.1002/anie.201908495
(2019)
Chemoselective (trans)thioacetalization of carbonyl compounds with a reusable lewis acid-surfactant-combined copper bis(dodecyl sulfate) catalyst in water

Doi:10.1055/s-0029-1218693
(2010)
1,6-Asymmetric induction in reactions between 6-hydroxy-6-methylhex-2-enyl(tributyl)stannane and aldehydes promoted by tin(IV) bromide

Doi:10.1016/0040-4039(95)00496-Y
(1995)
The reaction between epichlorohydrin and polysaccharides: Part 2, synthesis of some model substances, with cyclic substituents

Doi:10.1016/0008-6215(94)00293-O
(1995)

Article Doi