Migratory aptitude of the Zr-C functionalities bonded to a macrocyclic structure: Thermally- and solvent-assisted intra- and intermolecular migrations in dialkyl(dibenzotetramethyltetraazaannulene)zirconium(IV)

DOI: 10.1021/ja00126a019

Source and publish data:

Journal of the American Chemical Society p. 5801 - 5811 (1995)

Update date:2022-08-05

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Authors:

Giannini, Luca

Solari, Euro

De Angelis, Stefania

Ward, Thomas R.

Floriani, Carlo

Chiesi-Villa, Angiola

Rizzoli, Corrado

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Article abstract of DOI:10.1021/ja00126a019

The Zr-C bond chemistry and, particularly, its migration properties have been investigated where the metal is bonded to the dibenzotetramethyltetraaza[14]annulene (tmtaa) dianion in the model complexes cis-[Zr-(tmtaa)R₂]. In this respect the [Z

Full text of DOI:10.1021/ja00126a019

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