Preparation and Characterisation of (PR3)2>Cl (R = alkyl or aryl); Crystal Structure of >0.5EtOH0.3CH2Cl2

DOI: 10.1039/DT9950002489

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2489 - 2496 (1995)

Update date:2022-08-05

Topics:

Authors:

Bhattacharyya, Pravat

Slawin, Alexandra M. Z.

Williams, David J.

Woollins, J. Derek

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950002489

Reaction of NH(PPh2)2 with selenium gives Ph2P(Se)NHP(Se)Ph2 which may be deprotonated with KOBu-t to give K.This can be treated with appropriate Group VIII metal complexes to give (cod)> (cod = cycloocta-1,5-diene), a series of complexes of formula (PR3)2>Cl (PR3 = PMe3, PMe2Ph, PEt3, 1/2NH(PPh2)2 or 1/2Ph2PCH2CH2PPh2) and (PMe2Ph)> (M = Pt or Pd).The new compounds have been characterised by 31P and 195Pt NMR and IR spectroscopy, FAB(1+) mass spectrometry and microanalyses.Furthermore, a small quantity of a mixed-ligand complex >*0.5EtOH*0.3CH2Cl2 has been characterised by X-ray crystallography and 31P NMR spectroscopy.Its structure reveals an approximately planar five-membered PdSeP2N ring and a puckered six-membered PdSe2P2N ring.In the crystal the molecules pack with channels which contain the disordered CH2Cl2 molecules running down the a direction.

Full text of DOI:10.1039/DT9950002489

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Pt(N(SePPh₂)2-Se,Se')(PPh₃)2]Cl

Cas No:167774-29-0

R&D Labs maybe for 167774-29-0

Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
Zhejiang Rongkai Chemical Technology Co.,Ltd.

Contact:+86-578-8185786

Address:Shangjiang Industrial Zone,Suichang
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China
Afine Chemicals Limited

website:http://www.afinechem.com

Contact:+86-571-85134551

Address:No. 206 Zhen Hua Road, Hangzhou 310030, Zhejiang, China
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang

Relevant to this article

Bis-Adeninyl and Bis-Uracilyl Hexadiyne Derivatives of Nucleobases

Doi:10.1016/0040-4039(95)00751-W
(1995)
CO-transfer carbonylation reactions. A catalytic pauson-khand-type reaction of enynes with aldehydes as a source of carbon monoxide

Doi:10.1021/ja0126881
(2002)
Zirconium-assisted aldol condensation reactions of amido enolates: Structural and kinetic analysis of the reaction of N,N-diphenylacetamide and N,N-diphenylpropionamide enolates with benzaldehyde and p-substituted acetophenones

Doi:10.1021/om00009a012
(1995)
Phosphodiester hydrolysis by a new zinc(II) macrocyclic tetraamine complex with an alcohol pendant: Elucidation of the roles of ser-102 and zinc(II) in alkaline phosphatase

Doi:10.1021/ja00137a002
(1995)
Structure-activity relationships study at the 3'-N position of pactilaxel. Part 2: Synthesis and biological evaluation of 3'-N-thiourea- and 3'-N-thiocarbamate-bearing paclitaxel analogues

Doi:10.1016/S0960-894X(00)00242-0
(2000)
SYNTHETIC ANTICONVULSANTS, ANTIHYPOXICS, AND INDUCERS OF THE LIVER MONOOXYGENASE SYSTEM BASED ON AMIDES AND UREAS. XVII. SYNTHESIS OF N-BENZHYDRYL-N'(HETEROYL)UREAS AND STUDIES OF THEIR ANTICONVULSIVE ACTIVITY

Doi:10.1007/BF02219027
(1994)

Article Doi

Preparation and Characterisation of (PR3)2>Cl (R = alkyl or aryl); Crystal Structure of >*0.5EtOH*0.3CH2Cl2

DOI: 10.1039/DT9950002489

Source and publish data: