Diastereoselective synthesis of N-benzoyl mycalamine, the fully elaborated trioxadecalin nucleus of mycalamide. A. Control of the key N-acyl aminal stereocenter via carbamate acylation

DOI: 10.1016/0040-4039(95)00093-R

Source and publish data:

Tetrahedron Letters p. 1581 - 1584 (1995)

Update date:2022-07-31

Topics:

Authors:

Marron, Thomas G.

Roush, William R.

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Article abstract of DOI:10.1016/0040-4039(95)00093-R

A highly diastereoselective synthesis of N-benzoyl mycalamine (8), corresponding to the C(10)-C(18) amine fragment of mycalamide A, is described. The synthesis features a highly stereoselective acylation of carbamate 7 that permits the stereochemistry of

Full text of DOI:10.1016/0040-4039(95)00093-R

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