Synthesis of bis(tert-butyl)cyclopentadienyl derivatives of titanium and zirconium. NMR spectra and dynamic behaviour of the base-free 5-C5H3)(CH2Ph)2>+ cation

DOI: 10.1016/0022-328X(95)00116-8

Source and publish data:

Journal of Organometallic Chemistry p. 127 - 132 (1995)

Update date:2022-08-04

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Authors:

Amor, Jose Ignacio

Cuenca, Tomas

Galakhov, Mikhail

Royo, Pascual

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Article abstract of DOI:10.1016/0022-328X(95)00116-8

Reaction of Si(1,3-t-Bu2-C5H3)Me3 with MCl4 (M=Ti, Zr) intoluene or hexane at room temperature affords the new trichloromonociclopentadienyl-type derivatives 5-C5H3)Cl3> (M=Ti (2), Zr (3)>.Treatment of complexes 2 and 3 with appro

Full text of DOI:10.1016/0022-328X(95)00116-8

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