Facile Insertion of Alkynes into Ir-P (Phosphine) and Ir-As (Arsine) Bonds: Second and Third Alkyne Addition to Mononuclear Iridium Complexes

DOI: 10.1039/c39950001495

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1495 - 1496 (1995)

Update date:2022-08-04

Topics:

Authors:

Chin, Chong Shik

Park, Yongchul

Kim, Jinkyung

Lee, Byeongno

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001495

Alkynes (HCCH, PhCCH) insert into Ir-P (phosphine) and Ir-As (arsine) bonds of + and )(MeCN)(L3)>+ in the presence of MPh3, to produce + and (L3)(CH=CHR-M+P

Full text of DOI:10.1039/c39950001495

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₄H₄Ir(CO)[P(C₆H₅)3]2CHCHP(C₆H₅)3⁽¹⁺⁾*ClO₄^(1-)=C₄H₄Ir(CO)[P(C₆H₅)3]2CHCHP(C₆H₅)3ClO₄

Cas No:169230-47-1

R&D Labs maybe for 169230-47-1

Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
Fusilin chemical science & technology co., ltd.

Contact:532-80698166/86057573, +86-400-669-7885

Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong

Relevant to this article

Pentacoordinate Allylsiliconates in Organic Synthesis: Synthesis of Triethylammonium Bis(catecholato)allylsiliconates and Selective Allylation of Aldehydes

Doi:10.1021/jo00295a033
(1990)
HETEROCYCLIC KETONES AS PRE-FORMED BUILDING BLOCKS. SYNTHESIS OF (-)-SLAFRAMINE.

Doi:10.1016/0040-4039(95)01379-V
(1995)
Simple Approach Towards the Synthesis of 5-Methyl-2-hydroxypyrazine Derivatives from Dipeptidyl Chloromethyl Ketones

Doi:10.1016/0040-4039(94)88031-X
(1994)
Asymmetric synthesis of highly enantiomerically enriched (S)(-)-β-bisabolene

Doi:10.1080/00397919508011421
(1995)
Cleavage of pentafluorophenyl-phosphorus and -sulfur bonds by ethylmagnesium bromide

Doi:10.1016/S0022-1139(00)82419-7
(1992)
Doi:10.1021/ja01131a044
(1952)

Article Doi