(Ammine)(aqua)copper(II)

Article abstract of DOI:10.1107/S0108270194015064

The structure of the title compound <(ammine)(aqua)(2,6-dimethylphenyliminodiacetato-N,O,O )copper(II)> consists of discrete neutral molecules.The Cu atom is five-coordinate, with four short bonds formed with the N atom and two O atoms of the doubly deprotonated ligand and the N atom of the ammonia molecule.The water molecule is coordinated in an axial position at a longer distance.The coordination polyhedron can be described as a square-based pyramid with a small trigonal-bipyramidal distortion.