Thermal rearrangement of enantioenriched α-hydroxy imines -I. Enantiocontrolled synthesis of α-substituted α-amino ketones

DOI: 10.1016/0040-4039(95)00680-B

Source and publish data:

Tetrahedron Letters p. 4059 - 4062 (1995)

Update date:2022-08-04

Topics:: Authors:

Compain, Philippe

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Article abstract of DOI:10.1016/0040-4039(95)00680-B

Enantioenriched 2-allyl- and 2-(3-trimethylsilylpropargyl)-2-hydroxycyclohexanone were respectively obtained by resolution from the corresponding diastereomeric acetal derived from C₂-symmetrical diol or from the camphanate ester. Study of the rearrangement of their corresponding imine derivatives has shown that it occurred with complete retention of the stereogenicity.

Full text of DOI:10.1016/0040-4039(95)00680-B

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Article Doi

Thermal rearrangement of enantioenriched α-hydroxy imines -I. Enantiocontrolled synthesis of α-substituted α-amino ketones

DOI: 10.1016/0040-4039(95)00680-B

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0040-4039(95)00680-B

Full text of DOI:10.1016/0040-4039(95)00680-B

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