
Journal of Fluorine Chemistry p. 83 - 86 (1995)
Update date:2022-08-05
Topics:
Laduron, Frederic
Janousek, Zdenek
Viehe, Heinz, G.
The syntheses of α- and β-trifluoromethyl epoxysulfones 1 and 2 are described.Compound 1 reacts with nucleophiles and bis-nucleophiles to furnish trifluoromethyl ketones and trifluoromethyl heterocycles in good yield, while its isomer 2 leads to the opposite thiazole regioisomers with thioamides. - Keywords: Trifluoromethyl epoxysulfones; Heterocyclisation; Regioisomers; NMR spectroscopy; IR spectroscopy
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Doi:10.1021/jo952093m
(1996)Doi:10.1039/c39950001345
(1995)Doi:10.1016/0040-4039(95)01260-O
(1995)Doi:10.1016/0040-4039(95)01236-B
(1995)Doi:10.1007/BF00915683
()Doi:10.1016/0040-4039(94)88049-2
(1994)