Reactions of Rh-and Ir-bis(iminophosphoranyl)methanide compounds with electrophiles; a traped cation-anion complex in the oxidative addition of iodine to d8 metal centre and X-ray crystal structure of[IrI{CH(PPh2+N-C6H4-CH3-4)2}(COD)]I, containing two fus

DOI: 10.1016/0020-1693(95)90048-B

Source and publish data:

Inorganica Chimica Acta p. 77 - 88 (1995)

Update date:2022-08-03

Topics:

Authors:

Imhoff, Pieter

Guelpen, Jan H.

Vrieze, Kees

Smeets, Wilberth J. J.

Spek, Anthony L.

Elsevier, Cornelis J.

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Article abstract of DOI:10.1016/0020-1693(95)90048-B

Reaction of square planar M{CH(PPh2=N-C6H4-CH3-4)2}(COD)] (1a: M=Rh; 1b:M=Ir), in which the bis-iminophosporanylmethanide ligand is bidentate N ,C-coordinated, with I2, MeI and MeOSO2CF3 yields products resulting from metal or ligand (N atom) centered rea

Full text of DOI:10.1016/0020-1693(95)90048-B

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