Is it Possible to stabilise Complexes with a Tungsten-Phosphorus Triple Bond?

DOI: 10.1039/c39950001671

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1671 - 1672 (1995)

Update date:2022-08-04

Topics:

Authors:

Scheer, Manfred

Schuster, Kay

Budzichowski, Theodore A.

Chisholm, Malcolm H.

Streib, William E.

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Article abstract of DOI:10.1039/c39950001671

4-(Bu^t2C2P2)W(CO)5><η²-(Bu^tCP)W(CO)5>> 1 is prepared by treatment of Bu^tCP with ; the reaction of t)6> with Bu^tCP in the presence of (M = Cr, W) affords novel compounds of the type <(Bu^tO)3WP -> M(CO)5> (M = Cr, W), the first examples of a formal WP containing complex.

Full text of DOI:10.1039/c39950001671

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