
Acta Crystallographica, Section C: Crystal Structure Communications p. 67 - 69 (1999)
Update date:2022-08-04
Topics:
Otto, Stefanus
Mzamane, Sibusisiwe N.
Roodt, Andreas
The crystal structure of the square-planar title compound, [RhCl(C21H21P)2(CO)], describes another of the Vaska-type complexes. It is isomorphous with selected IrI and even PtII structures. Important bond lengths include Rh - P1 2.3344 (11), Rh - P2 2.3305 (11), Rh - Cl 2.3581 (12), Rh - Cl 1.798 (5) and Cl - O1 1.139 (6) A.
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