trans-Carbonylchlorobis(tri-p-tolylphosphine)rhodium(I)

DOI: 10.1107/S0108270198011603

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 67 - 69 (1999)

Update date:2022-08-04

Topics:

Authors:

Otto, Stefanus

Mzamane, Sibusisiwe N.

Roodt, Andreas

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Article abstract of DOI:10.1107/S0108270198011603

The crystal structure of the square-planar title compound, [RhCl(C₂₁H₂₁P)₂(CO)], describes another of the Vaska-type complexes. It is isomorphous with selected Ir^I and even Pt^II structures. Important bond lengths include Rh - P1 2.3344 (11), Rh - P2 2.3305 (11), Rh - Cl 2.3581 (12), Rh - Cl 1.798 (5) and Cl - O1 1.139 (6) A.

Full text of DOI:10.1107/S0108270198011603

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