Tetrahedron p. 2839 - 2847 (2005)
Update date:2022-08-04
Topics:
Volochnyuk, Dmitriy M.
Kostyuk, Alexander N.
Sibgatulin, Dmitriy A.
Chernega, Alexander N.
The reaction of 1,1,1,5,5,5-hexafluoroacetylacetone with push-pull enamines having a methyl group at the α-position was investigated. It was found that the reaction is sensitive both to the structure of enamines and to reaction conditions. As a result, a set of bistrifluoromethyldialkylanilines and ethyl bistrifluoromethylsalicylate was prepared. Plausible mechanisms and factors influencing the course of the reaction are discussed.
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