Synthesis and characterization of two new molybdenum(0) σ-aryl complexes of the type [N(PPh3)2][Mo(C6F5)L(CO)2{P(OMe)3}2]: X-ray crystal structure of bis(triphenylphosphine)iminium pentafluorophenyl(mer-tricarbonyl)trans-bis(trimethylphosphite)molybdate(0

DOI: 10.1016/0277-5387(94)00499-5

Source and publish data:

Polyhedron p. 2215 - 2220 (1995)

Update date:2022-09-26

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Authors:

Mullica, D. F.

Gipson, S. L.

Su, M. Su, M.

Sappenfield, E. L.

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Article abstract of DOI:10.1016/0277-5387(94)00499-5

The complex [cis-mer-Mo(C6F5)(CO)2{P(OMe)3}3](-) reacts with the π-acid ligands CO and (t)BuNC to yield the substitution products [Mo(C6F5)L(CO)2{P(OMe)3}2](-), both isolated as the N(PPh3)2(+) salts. Both new complexes have been fully characterized by IR

Full text of DOI:10.1016/0277-5387(94)00499-5

Products guided by the article

Product name:N(P(C₆H₅)3)2⁽¹⁺⁾*Mo(C₆F₅)(CO)3(P(OCH₃)3)2^(1-)=[N(P(C₆H₅)3)2][Mo(C₆F₅)(CO)3(P(OCH₃)3)2]

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