Tetrahedron p. 8175 - 8188 (1995)
Update date:2022-08-03
Topics:
Lange, Steven J.
Sibert, John W.
Stern, Charlotte L.
Barrett
Hoffman, Brian M.
A general synthetic method for incorporation of the dithiomaleonitrile unit into macrocycles containing sulfur, oxygen and nitrogen heteroatoms is presented along with the single-crystal X-ray structures of the thiacrowns. In addition to being new ligands, these macrocycles are direct precursors to peripherally crown functionalized porphyrazines capable of coordinating multiple metal ions.
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Doi:10.1021/ja00148a024
(1995)Doi:10.1055/s-1997-1540
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(1995)
