Tetrahedron p. 8613 - 8622 (1995)
Update date:2022-07-30
Topics:
Bartoli, Giuseppe
Cimarelli, Cristina
Dalpozzo, Renato
Palmieri, Gianni
A versatile route to β-enamino esters 1, using accessible starting materials, was developed. Lithiated enamines are allowed to react with diethyl carbonate or benzyl chloroformate with the formation of the β-enamino esters 1a or 1b. The reaction is rather general from a wide array of ketimines and aldimines. Products included cyclic β-enamino esters 1aa-ac, very useful for the synthesis of natural products.
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Doi:10.1007/s004100000214
()Doi:10.1016/0223-5234(96)88274-2
(1995)Doi:10.1016/0040-4020(95)00557-O
(1995)Doi:10.1016/00404-0399(50)1328-F
(1995)Doi:10.1021/ja01622a055
(1955)Doi:10.1016/0040-4039(96)01282-8
(1996)
