Synthesis and crystal structure of a pentacoordinate 1,2-oxagermetanide

DOI: 10.1016/0022-328X(95)00302-7

Source and publish data:

Journal of Organometallic Chemistry p. 143 - 146 (1995)

Update date:2022-08-05

Topics:

Authors:

Kawashima, Takayuki

Nishiwaki, Yuri

Okazaki, Renji

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Article abstract of DOI:10.1016/0022-328X(95)00302-7

A pentacoordinate 1,2-oxagermetanide 1, K⁺ 18-crown-6 <<-C6H4C(CF3)2O->GePh<-CH(CH2^tBu)C(CF3)2O-)>^-, was quantitatively synthesized as a colourless block (m.p. 217-218 deg C (decomp.)) by deprotonation of the corresponding

Full text of DOI:10.1016/0022-328X(95)00302-7

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Product name:(3,3-dimethylbutyl)diphenyl-(2-[2,2,2-trifluoro-1-hydroxy-1-(trifluoromethyl)ethyl]phenyl)germane

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