Enzymatic desymmetrization of meso(anti-anti)-2,4-dimethyl-1,3,5-pentanetriol

DOI: 10.1016/0957-4166(95)00272-Q

Source and publish data:

Tetrahedron Asymmetry p. 2093 - 2096 (1995)

Update date:2022-08-03

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Authors:

Chenevert

Courchesne

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Article abstract of DOI:10.1016/0957-4166(95)00272-Q

The stereoselective acetylation of meso-3-(tert-butyldimethylsiloxy)-2,4-dimethyl-1,5-pentanediol by vinyl acetate in the presence of Candida rugosa lipase in organic medium gave the corresponding (2R, 3R, 4S) mono ester in high enantiomeric purity (ee =

Full text of DOI:10.1016/0957-4166(95)00272-Q

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Product name:Acetic acid (2S,3R,4R)-5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentyl ester

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