Synthesis p. 1097 - 1101 (1995)
Update date:2022-08-03
Topics:
Weinmann
Winterfeldt
Cycloadduct 9 was transformed into vinylsilane 11d in a conjugate addition-alkylation sequence. Epoxidation and subsequent hydrolysis provided the clavularin adduct 14, which on flash vacuum pyrolysis (FVP) gave (+)-clavularin A (1) in 91% yield.
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Doi:10.1016/0008-6215(95)00031-N
(1995)Doi:10.1021/jo00897a012
(1975)Doi:10.1021/ja991749g
(1999)Doi:10.1002/cmdc.201600258
(2016)Doi:10.1039/c6cc05456k
(2016)Doi:10.1039/c39950002005
(1995)
