Journal of the Chemical Society. Chemical communications p. 1787 - 1788 (1995)
Update date:2022-08-04
Topics:
Liu
Cheung
Peng
Che
Two gold complexes, [Au(III){4-MeOPh-(Phbipy)}Cl]·CF3SO3 1 and [Au(III)(4-MeOPh-terpy)Cl]·(ClO4)2 2 [4-MeOPh-(Phbipy) = 4'-(4-methoxyphenyl)-6'-phenyl-2,2'-bipyridine, 4-MeOPh-terpy = 4'-(4-methoxyphenyl)-2,2',6',2'-terpyridine] are prepared, and their interactions with calf-thymus DNA, poly(dG-dC)2 and poly(dA-dT)2, investigated by spectroscopic means; in the reaction with ct DNA, 1 has a higher binding constant than 2, but the latter has a higher degree of AT specificity.
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