Russian Chemical Bulletin p. 931 - 936 (1995)
Update date:2022-08-04
Topics: Synthesis Chemical reactions Reactants Structure Experimental Methods
Sharutin, V. V.
Zhidkov, V. V.
Muslin, D. V.
Liapina, N. Sh.
Fukin, G. K.
et al.
A series of aroxytetraphenylstiboranes, Ph4SbOAr, were obtained by the reaction of pentaphenylstiborane with phenols at ca.20 deg C.The thermolysis of these compounds gives O- or o-C-phenylation products.The thermolysis of stiboranes, which incorporate aryl groups containing electron-withdrawing substituents (Ar = 2,4-Br2, 2,4-Cl2, 2-NO2, 4-OPh) produces predominantly simple diaryl ethers of asymmetric structure in 58percent, 90percent, 32percent, and 60percent yields, respectively.
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(1996)
