Green Chemistry p. 7328 - 7332 (2020)
Update date:2022-08-02
Topics:
Cai, Lei
Fu, Lei
Gao, Yuzhen
Li, Gang
Li, Shangda
Zhou, Chunlin
The first Rh(i)-catalyzed regioselective arylcarboxylation of electron-deficient acrylamides with arylboronic acids under atmospheric pressure of CO2 has been developed. A range of acrylamides and arylboronic acids were compatible with this reaction under redox-neutral conditions, leading to a series of malonate derivatives that are versatile building blocks in organic syntheses.
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