Journal of Organic Chemistry p. 7870 - 7878 (1995)
Update date:2022-08-03
Topics:
Banfi, Luca
Guanti, Giuseppe
Zannetti, Maria Teresa
All possible stereoisomers of triols of general formula 5 (R1=allyl, R2=Me or allyl) have been synthesized stereoselectively starting from asymmetrized bis(hydroxymethyl)acetaldehyde (BHYMA), a novel chiral building block prepared through a chemoenzymatic methodology.This goal was realized through a sequence of protecting group-controlled nucleophilic additions and/or reductions performed on two side arms of this versatile building block.
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Doi:10.1248/cpb.29.1870
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(1981)