Formal synthesis of (±)-upial. Oxidative free-radical cyclization of unsaturated 1,3-cyclohexanediones

DOI: 10.1016/0040-4020(95)00841-U

Source and publish data:

Tetrahedron p. 12983 - 12994 (1995)

Update date:2022-08-03

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Authors:

Snider, Barry B.

O'Neil, Steven V.

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Article abstract of DOI:10.1016/0040-4020(95)00841-U

Oxidative free-radical cyclization of 4-(3-hexenyl)-1,3-cyclohexanedione 8 affords 85% of a mixture of 7 and 29. Short sequences were developed to convert this mixture to 2, a late intermediate in Taschner's synthesis of upial.

Full text of DOI:10.1016/0040-4020(95)00841-U

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