Stereochemical assignment of the C35-C39 acyclic linkage in maitotoxin: Completion of stereochemical determination of C15-C134

DOI: 10.1016/0040-4039(95)01973-L

Source and publish data:

Tetrahedron Letters p. 9011 - 9014 (1995)

Update date:2022-08-04

Topics:

Authors:

Sasaki, Makoto

Matsumori, Nobuaki

Murata, Michio

Tachibana, Kazuo

Yasumoto, Takeshi

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Article abstract of DOI:10.1016/0040-4039(95)01973-L

The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in ¹H and ¹³C NMR spectra. This result completed stereochemical assignments of the whole molecule except for side chains.

Full text of DOI:10.1016/0040-4039(95)01973-L

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