Tetrahedron Letters p. 7097 - 7100 (1995)
Update date:2022-08-04
Topics:
Satoh
Takano
Someya
Matsuda
The first example of magnesium alkylidene carbenoids is described. 1-Halovinyl sulfoxides 3 (X = F, Cl, Br) were synthesized from ketones and aryl halomethyl sulfoxides in three steps in moderate to good overall yields. Ligand exchange reaction of the sulfoxides of 3 with ethylmagnesium halide in THF at low temperature afforded a magnesium alkylidene carbenoid, which reacted with several electrophiles to give new alkylidene compounds.
View MoreShijiazhuang City Xiehe Pharmaceutical Co., Ltd
Contact:+86-311-80817929
Address:Shangzhuang,Shijiazhuang,China
Zhejiang Kente Chemical Co.,Ltd.
Contact:86-0576-87651912
Address:No.7, Fengxi West Road, Modern Industrial Zone
Contact:+86-021-50792271
Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Contact:+65 9658 0999
Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
Shandong Wanda Organosilicon New Material Co., Ltd
Contact:+86-21-54177116;54302881
Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
Doi:10.1021/om950574q
(1996)Doi:10.1021/ja00151a030
(1995)Doi:10.1055/s-2006-942359
(2006)Doi:10.1038/s41429-019-0221-9
(2019)Doi:10.1016/0040-4039(95)01725-W
(1995)Doi:10.1016/S0040-4020(01)89776-3
(1990)
