Tetrahedron Letters p. 7097 - 7100 (1995)
Update date:2022-08-04
Topics:
Satoh
Takano
Someya
Matsuda
The first example of magnesium alkylidene carbenoids is described. 1-Halovinyl sulfoxides 3 (X = F, Cl, Br) were synthesized from ketones and aryl halomethyl sulfoxides in three steps in moderate to good overall yields. Ligand exchange reaction of the sulfoxides of 3 with ethylmagnesium halide in THF at low temperature afforded a magnesium alkylidene carbenoid, which reacted with several electrophiles to give new alkylidene compounds.
View MoreAnhui Biochem United Pharmaceutical Co., Ltd.
Contact:0086 551 5167062 / 5228268
Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Contact:+86-731-84427351
Address:154 JIANXIANG SOUTH ROAD
Weifang Yukai Chemical Co.,Ltd.
website:http://www.yukaichem.com/en.html
Contact:+86-536-8865336
Address:binhai economic development zone,262737 shangdong,china
website:http://www.uvchemkeys.com
Contact:0086-021-58785816
Address:RM2607 Building No.1 Guosheng, Lane 388, Zhongjiang Road, Putuo District, Shanghai 200062 China
YanCheng LongShen Chemical Co.,Ltd.
Contact:+86-515-86668866
Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Doi:10.1021/om950574q
(1996)Doi:10.1021/ja00151a030
(1995)Doi:10.1055/s-2006-942359
(2006)Doi:10.1038/s41429-019-0221-9
(2019)Doi:10.1016/0040-4039(95)01725-W
(1995)Doi:10.1016/S0040-4020(01)89776-3
(1990)