Diastereoselective synthesis of merucathin: The singlet oxygen ene reaction (Schenck reaction) as a key step towards an E-configured β-amino allylic alcohol

DOI: 10.1055/s-1995-4071

Source and publish data:

Synthesis p. 1066 - 1068 (1995)

Update date:2022-08-02

Topics:

Authors:

Adam Adam

Brunker Brunker

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1995-4071

An enantio- and diastereoselective synthesis of the naturally occurring merucathin is reported. The singlet oxygen ene reaction of the bis-Boc-protected allylic amine 3, which was prepared from L-alanine, was employed as key step for this regio- and diast

Full text of DOI:10.1055/s-1995-4071

Products guided by the article

Product name:(S,Z)-bis(1,1-dimethylethyl) N-(1-methyl-4-phenylbut-2-enyl)-imidodicarbonate

Cas No:172472-87-6

R&D Labs maybe for 172472-87-6

Chongqing Changfeng Chemical Co., Ltd.

website:http://www.changfengchem.com

Contact:+86-23-67896333

Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Changyi Xinxing Technology Development Co., Ltd.

Contact:0086-510-86651065(Time Zone:8),86651656

Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Quzhou Aokai Chemical Co., Ltd.

Contact:86-570-3032832

Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
XZL BIO-TECHNOLOGY CO., LTD.

Contact:0086 533 2282832

Address:Zibo，Shandong
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING

Relevant to this article

Reaction of N-Benzoyl Amino Acids with Oxalyl Chloride: a Facile Route to 4-Substituted 2-Phenyloxazole-5-carboxylates

Doi:10.1039/c39950002335
(1995)
Concise total synthesis of (±)-palominol and (±)-dolabellatrienone via a dianion-accelerated oxy-Cope rearrangement

Doi:10.1016/S0040-4039(97)10614-1
(1998)
Syntheses of 1-O-carboxyalkyl GLA-60 analogues

Doi:10.1016/0008-6215(95)00402-5
(1996)
Doi:10.1021/jo01031a067
(1964)
Improving reactivity and selectivity of aqueous-based Heck reactions by the local hydrophobicity of phosphine ligands

Doi:10.1016/j.tet.2015.09.010
(2015)
Reaction of 5-Amino-1-phenylpyrazole-4-carbonitriles with Dimethyl Acetylenedicarboxylate. Synthesis and Structural Determination of Trimethyl 4,8-Dioxo-1-phenyl-4,5,5a,8-tetrahydro-1H-pyrazolo[3,4-e]indolizine-5,5a,6- tricarboxylate Derivatives

Doi:10.1002/jhet.5570340244
(1997)

Article Doi