Stereoselective Synthesis of 2,5-Dialkyl-3-(phenylsulfonyl) Tetrahydrofurans via Cyclisation of Z-Sulfonyl-substituted Homoallylic Alcohols

DOI: 10.1016/0040-4039(95)01524-8

Source and publish data:

Tetrahedron Letters p. 7531 - 7534 (1995)

Update date:2022-08-03

Topics:

Authors:

Craig, Donald

Ikin, Neil J.

Mathews, Neil

Smith, Alison M.

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Article abstract of DOI:10.1016/0040-4039(95)01524-8

Z-Sulfonyl-substituted homoallylic alcohols 3 underwent highly anti-selective base-mediated 5-endo-trig cyclisation reactions to give 2,5-dialkyl-3-phenylsulfonyl tetrahydrofurans anti-2.A simple steric model is proposed to account for the high selectivit

Full text of DOI:10.1016/0040-4039(95)01524-8

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