A New Access to Mori's Intermediate for the Practical Synthesis of (-)-Periplanone-B

DOI: 10.1246/cl.1995.1091

Source and publish data:

Chemistry Letters p. 1091 - 1092 (1995)

Update date:2022-08-02

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Authors:

Hashimoto, Shun-ichi

Miyazaki, Yoji

Shiro, Motoo

Ikegami Shiro

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Article abstract of DOI:10.1246/cl.1995.1091

Mori's key intermediate 2 for the large-scale synthesis of (-)-periplanone-B has been prepared from β-keto prenyl ester 8 by exploiting the new three-step sequence of α-alkynylation with alkynyllead(IV) triacetate, semihydrogenation, and palladiumcatalyze

Full text of DOI:10.1246/cl.1995.1091

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