Addition of dimethyloxosulfonium methylide to enantiomerically pure sulfinimines: Asymmetric synthesis of 2-substituted aziridines

DOI: 10.1016/0957-4166(95)00185-R

Source and publish data:

Tetrahedron Asymmetry p. 1511 - 1514 (1995)

Update date:2022-07-29

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Authors:

Davis Davis

Zhou Zhou

Liang Liang

Reddy Reddy

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Article abstract of DOI:10.1016/0957-4166(95)00185-R

Diastereoselective addition of dimethyloxosulfonium methylide to chiral nonracemic pure sulfinimines 1 affords N-sulfinyl aziridines 3 in 58-70% de which are readily separated. The N-sulfinyl auxillary in 3 was removed, without ring-opening, by treatment

Full text of DOI:10.1016/0957-4166(95)00185-R

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Product name:(S)-2-Naphthalen-1-yl-1-((S)-toluene-4-sulfinyl)-aziridine

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