Tetrahedron Letters p. 7035 - 7038 (1992)
Update date:2022-07-29
Topics:
Inanaga
Sugimoto
Hanamoto
2,3-Naphthoquinodimethanes are easily generated from o-bis(α-acetoxypropargyl)benzene derivatives with SmI2 in the presence of palladium catalyst under mild conditions. The reactions of the quinodimethane intermediates were found to follow the different paths depending on the acetylenic substituents of substrates.
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