1,1'-Bis(diphenylthiophosphoryl)ferrocene as a trans-Chelating Ligand in Gold(I) and Silver(I) Complexes

DOI: 10.1039/DT9950003563

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3563 - 3564 (1995)

Update date:2022-08-04

Topics:

Authors:

Gimeno, M. Concepcion

Jones, Peter G.

Laguna, Antonio

Sarroca, Cristina

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Article abstract of DOI:10.1039/DT9950003563

The reaction of 1,1'-bis(diphenylthiophosphoryl)ferrocene (dptpf) with AgClO4 or CF3SO3 (tht = tetrahydrothiophene) in a 1:1 molar ratio led to complexes of the stoichiometry (+).The crystal structures of both complexes revealed a linear co-ordination geometry with a novel trans co-ordination by the ligand.

Full text of DOI:10.1039/DT9950003563

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